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Enhancing U(eff) in oxime-bridged [Mn(III)6Ln(III)2] hexagonal prisms.

Authors :
Rigaux G
Inglis R
Morrison S
Prescimone A
Cadiou C
Evangelisti M
Brechin EK
Source :
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2011 May 14; Vol. 40 (18), pp. 4797-9. Date of Electronic Publication: 2011 Mar 29.
Publication Year :
2011

Abstract

The first 3d-4f clusters built using derivatised salicylaldoximes (R-saoH(2)) describe unusual hexagonal prisms. Replacement of the paramagnetic Gd(III) ions with diamagnetic Ln(III) ions allows for a more thorough understanding of the magnetic properties, whilst replacement with Tb(III) doubles U(eff).

Details

Language :
English
ISSN :
1477-9234
Volume :
40
Issue :
18
Database :
MEDLINE
Journal :
Dalton transactions (Cambridge, England : 2003)
Publication Type :
Academic Journal
Accession number :
21448490
Full Text :
https://doi.org/10.1039/c1dt10154d