Saccharification of natural lignocellulose biomass and polysaccharides by highly negatively charged heteropolyacids in concentrated aqueous solution.

Highly negatively charged heteropolyacids (HPAs), in particular H(5) BW(12) O(40) , efficiently promoted saccharification of crystalline cellulose into water-soluble saccharides in concentrated aqueous solutions (e.g., 82 % total yield and 77 % glucose yield, based on cellulose with a 0.7 M H(5) BW(12) O(40) solution); the performance was much better than those of previously reported systems with commonly utilized mineral acids (e.g., H(2) SO(4) and HCl) and HPAs (e.g., H(3) PW(12) O(40) and H(4) SiW(12) O(40)). Besides crystalline cellulose, the present system was applicable to the selective transformation of cellobiose, starch, and xylan to the corresponding monosaccharides such as glucose and xylose. In addition, one-pot synthesis of levulinic acid and sorbitol directly from cellulose was realized by using concentrated HPA solutions. The present system, concentrated aqueous solutions of highly negatively charged HPAs, was further applicable to saccharification of natural (non-purified) lignocellulose biomass, such as "rice plant straw", "oil palm empty fruit bunch (palm EFB) fiber", and "Japanese cedar sawdust", giving a mixture of the corresponding water-soluble saccharides, such as glucose (main product), galactose, mannose, xylose, arabinose, and cellobiose, in high yields (≥77 % total yields of saccharides based on holocellulose). Separation of the saccharides and H(5) BW(12) O(40) was easy, and the retrieved H(5) BW(12) O(40) could repeatedly be used without appreciable loss of the high performance.
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