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Unprecedented bending and rearrangement of f-element sandwich complexes induced by superbulky cyclooctatetraenide ligands.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2011 Feb 09; Vol. 133 (5), pp. 1257-9. Date of Electronic Publication: 2011 Jan 07. - Publication Year :
- 2011
-
Abstract
- The use of the superbulky cyclooctatetraenide dianion ligand [C(8)H(6)(SiPh(3))(2)](2-) (= COT(BIG)) in organo-f-element chemistry leads to unprecedented effects such as the formation of a significantly bent anionic Ce(III) sandwich complex, a novel cerocene formed by sterically induced SiPh(3) group migration, as well as the first example of a bent uranocene.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 133
- Issue :
- 5
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 21214176
- Full Text :
- https://doi.org/10.1021/ja109604t