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2,4,6-Trimethyl-3-phenyl-sulfinyl-1-benzofuran.

Authors :
Choi HD
Seo PJ
Son BW
Lee U
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2008 Jul 12; Vol. 64 (Pt 8), pp. o1476. Date of Electronic Publication: 2008 Jul 12.
Publication Year :
2008

Abstract

The title compound, C(17)H(16)O(2)S, was prepared by the oxidation of 2,4,6-trimethyl-3-phenyl-sulfanyl-1-benzofuran with 3-chloro-peroxy-benzoic acid. The O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the planar benzofuran fragment. The phenyl ring is nearly perpendicular to the plane of the benzofuran unit [89.88 (8)°] and is tilted slightly towards it. The crystal structure is stabilized by C-H⋯π inter-actions between a phenyl H atoms and the phenyl and furan rings of neighbouring mol-ecules. In addition, the crystal structure exhibits inter-molecular C-H⋯O inter-actions.

Details

Language :
English
ISSN :
1600-5368
Volume :
64
Issue :
Pt 8
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21203188
Full Text :
https://doi.org/10.1107/S1600536808021090