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Dichloridobis[(1S,1S',2R,2R')-(+)-1,1'-di-tert-butyl-2,2'-diphospho-lane-κP,P']ruthenium(II).
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2008 May 03; Vol. 64 (Pt 6), pp. m754. Date of Electronic Publication: 2008 May 03. - Publication Year :
- 2008
-
Abstract
- In the title compound, [RuCl(2)(C(16)H(32)P(2))(2)], the Ru(II) ion is situated on a twofold rotation axis, so the asymmetric unit contains one half-mol-ecule. The slightly distorted octa-hedral environment of the Ru center is formed by four P atoms [Ru-P = 2.4417 (6) and 2.4544 (6) Å] from two different (1S,1S',2R,2R')-TangPhos ligands [(1S,1S',2R,2R')-TangPhos = (1S,1S',2R,2R')-(+)-1,1'-di-tert-butyl-2,2'-diphospho-lane] and two Cl atoms [Ru-Cl = 2.4267 (5) Å].
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 64
- Issue :
- Pt 6
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21202447
- Full Text :
- https://doi.org/10.1107/S1600536808008301