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Simultaneous self-assembly of a cage-like silver(I) complex encapsulating an Ag6 neutral cluster core and carbon dioxide fixation.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2011 Feb 07; Vol. 47 (5), pp. 1461-3. Date of Electronic Publication: 2010 Dec 16. - Publication Year :
- 2011
-
Abstract
- A novel mixed-valent Ag(I)/Ag(0) T(h)-Ag(34) cage was obtained by a one-pot ultrasonic reaction. In the shell of the cage, CO(3)(2-) anion is derived from atmospheric CO(2) and adopts a rare μ(6) bridging mode to link the Ag(I) ions. In the core of the cage, an unprecedented neutral metal cluster with six zero-valent silver atoms is encapsulated.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 47
- Issue :
- 5
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 21165465
- Full Text :
- https://doi.org/10.1039/c0cc04391e