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Photoinversion of sulfoxides as a source of diversity in dynamic combinatorial chemistry.
- Source :
-
Organic letters [Org Lett] 2011 Jan 07; Vol. 13 (1), pp. 142-5. Date of Electronic Publication: 2010 Dec 01. - Publication Year :
- 2011
-
Abstract
- Photochemical interconversion of the two diastereoisomers cis- and trans-thianthrene dioxide (1) can be considered an example of photodynamic combinatorial chemistry (PDCC) in which the interconversion among diastereomeric equilibrating species is brought about by electromagnetic irradiation. Photoequilibrium can be shifted by irradiation at different wavelengths or by addition of SnCl(2) that binds cis-1 more efficiently than trans-1.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 13
- Issue :
- 1
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 21121645
- Full Text :
- https://doi.org/10.1021/ol102715p