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Nitrile-rich coordination polymer (1)(∞){[Fe(CH(3)CN)(4)(pyrazine)](ClO(4))(2)} exhibiting a HS ⇆ LS transition.
- Source :
-
Inorganic chemistry [Inorg Chem] 2010 Dec 20; Vol. 49 (24), pp. 11267-9. Date of Electronic Publication: 2010 Nov 15. - Publication Year :
- 2010
-
Abstract
- In a 1D network of (1)(∞){[Fe(CH(3)CN)(4)(pyrazine)](ClO(4))(2)}, the presence of four neutral nitrile molecules besides the pyrazine donors in the first coordination sphere of iron(II) allows one to achieve a ligand field strength appropriate for the "spin-crossover" occurrence.
Details
- Language :
- English
- ISSN :
- 1520-510X
- Volume :
- 49
- Issue :
- 24
- Database :
- MEDLINE
- Journal :
- Inorganic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 21077596
- Full Text :
- https://doi.org/10.1021/ic102040y