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Simple combustion production and characterization of octahydro[60]fullerene with a non-IPR C60 cage.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2010 Nov 03; Vol. 132 (43), pp. 15093-5. - Publication Year :
- 2010
-
Abstract
- For the first time an easier, operable combustion method is employed for the synthesis of non-IPR fullerene, and an octahydro[60]fullerene with a non-IPR C(60) cage (C(60) isomer (#1809)C(60)) produced by combustion is isolated and characterized by MS, UV-vis, IR, and NMR spectroscopies in combination with DFT calculations. This finding shows that, in addition to chlorine, hydrogen can be an ample cataloreactant for the production of non-IPR fullerene derivatives under such conditions as arc-burning and diffusion combustion.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 132
- Issue :
- 43
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 20931962
- Full Text :
- https://doi.org/10.1021/ja108316e