Synthesis, characterization and property of a mixed-valent Ag(I)/Ag(II) coordination polymer.

Authors :: Sun D
Yang CF
Xu HR
Zhao HX
Wei ZH
Zhang N
Yu LJ
Huang RB
Zheng LS
Source :: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2010 Nov 21; Vol. 46 (43), pp. 8168-70. Date of Electronic Publication: 2010 Sep 28.
Publication Year :: 2010
Abstract: A novel mixed-valent Ag(I)/Ag(II) coordination polymer {[Ag(I)(2)Ag(II)(0.5)(SO(4))(HSO(4))(pyz)(2.5)]·H(2)O}(n) (1, pyz = pyrazine) was synthesized and characterized. The results show it presents semiconducting and photoluminescent properties.

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