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Diels-Alder reactions of cyclic isoimidium salts.
- Source :
-
Organic letters [Org Lett] 2010 Oct 15; Vol. 12 (20), pp. 4524-7. - Publication Year :
- 2010
-
Abstract
- Diels-Alder reactions of cyclic isoimidium salts are described. The corresponding cycloadducts are obtained with high regio- and stereoselectivity. The use of homochiral cyclic isoimidium salts delivers cycloadducts with excellent diastereoselectivity (>99:1) that can be efficiently converted to enantiomerically pure lactones.
- Subjects :
- Cyclization
Molecular Structure
Stereoisomerism
Imides chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 12
- Issue :
- 20
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 20843021
- Full Text :
- https://doi.org/10.1021/ol101831b