Synthesis, structures and electrochemistry studies of 2Fe2S-Fe(ii)(S-2N)(2) models for H-cluster of [FeFe]-hydrogenase.

Authors :: Hu MQ
Wen HM
Ma CB
Li N
Yan QY
Chen H
Chen CN
Source :: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2010 Oct 28; Vol. 39 (40), pp. 9484-6. Date of Electronic Publication: 2010 Sep 08.
Publication Year :: 2010
Abstract: A series of model complexes [(μ-pdt)Fe(2)(CO)(5)](2)M(sip)(2) (M = Fe, Ni) were synthesized as H-cluster analogues of [FeFe]-hydrogenase. Their electrochemical behaviours were investigated and it is proposed that the bridging metal bis(tris-chelate) groups act as electron transfer sites in theses mimics.

Subjects :: Coordination Complexes chemistry
Electrochemical Techniques
Electron Transport
Hydrogenase metabolism
Iron-Sulfur Proteins metabolism
Models, Molecular
Molecular Conformation
Coordination Complexes chemical synthesis
Hydrogenase chemistry
Iron-Sulfur Proteins chemistry

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