Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species.

Authors :: Herbert M
Alvarez E
Cole-Hamilton DJ
Montilla F
Galindo A
Source :: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2010 Aug 28; Vol. 46 (32), pp. 5933-5. Date of Electronic Publication: 2010 Jul 02.
Publication Year :: 2010
Abstract: The complex [Mo(4)O(16)(dmpz)(6)] (1) has been isolated as part of a study of oxodiperoxomolybdenum catalysed epoxidation of olefin substrates with hydrogen peroxide in ionic liquids. Notably, 1 is the first dioxoperoxomolybdenum species to be structurally characterised.

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