Back to Search
Start Over
Praseodymium(III)-based bis-metallacalix[4]arene with host-guest behaviour.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2010 May 14; Vol. 39 (18), pp. 4353-7. Date of Electronic Publication: 2010 Mar 24. - Publication Year :
- 2010
-
Abstract
- The reaction of Pr(NO(3))(3).6H(2)O with the ligand 2-hydroxy-N-(2'-hydroxyethyl)-3-methoxybenzamide (H(3)L) in MeOH-MeCN generates the nonanuclear compound [Pr(9)(H(2)L)(8)(OH)(10)(NO(3))(8)](NO(3))(H(2)O)(2)(CH(3)CN) (), whose single-crystal X-ray structure reveals the presence of metallacalix[4]arene cavities that host guest molecules. The crystal packing of the antiferromagnetic Pr(9) cluster shows an intricate network of hydrogen bonds producing a one-dimensional supramolecular chain.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 39
- Issue :
- 18
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 20422093
- Full Text :
- https://doi.org/10.1039/b925297e