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A detailed investigation of the aza-Prins reaction.

Authors :
Dobbs AP
Guesné SJ
Parker RJ
Skidmore J
Stephenson RA
Hursthouse MB
Source :
Organic & biomolecular chemistry [Org Biomol Chem] 2010 Mar 07; Vol. 8 (5), pp. 1064-80. Date of Electronic Publication: 2010 Jan 05.
Publication Year :
2010

Abstract

The development of a Lewis acid-promoted aza-Prins reaction to form piperidines and pyrrolidines is described. Indium trichloride has been found to be a highly successful and mild Lewis acid for promoting this reaction. A thorough mechanistic investigation is described, including the factors that influence the formation of the 5- or 6-membered ring product(s).

Details

Language :
English
ISSN :
1477-0539
Volume :
8
Issue :
5
Database :
MEDLINE
Journal :
Organic & biomolecular chemistry
Publication Type :
Academic Journal
Accession number :
20165797
Full Text :
https://doi.org/10.1039/b915797b