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Single and double substrate insertion into the Ti=N(alpha) bonds of terminal titanium hydrazides.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2010 Jan 07; Vol. 46 (1), pp. 85-7. Date of Electronic Publication: 2009 Nov 19. - Publication Year :
- 2010
-
Abstract
- Nitriles, CO(2) and isocyanates undergo net single or double insertion reactions into the Ti=N(alpha) multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 46
- Issue :
- 1
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 20024301
- Full Text :
- https://doi.org/10.1039/b920090h