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An air stable moisture resistant titanium triflate complex as a Lewis acid catalyst for C-C bond forming reactions.

Authors :
Bull SD
Davidson MG
Johnson AL
Mahon MF
Robinson DE
Source :
Chemistry, an Asian journal [Chem Asian J] 2010 Mar 01; Vol. 5 (3), pp. 612-20.
Publication Year :
2010

Abstract

An air and moisture stable C(3)-symmetric titanium(IV) triflate, supported by a tripodal amine-(tris-phenolate) ligand, has been synthesized and characterized by X-ray crystallography and shown to be a good Lewis acid catalyst for a range of aza-Diels-Alder, Diels-Alder, syn aldol, allylation, and alkylation reactions.

Details

Language :
English
ISSN :
1861-471X
Volume :
5
Issue :
3
Database :
MEDLINE
Journal :
Chemistry, an Asian journal
Publication Type :
Academic Journal
Accession number :
20013996
Full Text :
https://doi.org/10.1002/asia.200900305