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An enantiopure pseudo-C3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions.

Authors :
Axe P
Bull SD
Davidson MG
Jones MD
Robinson DE
Mitchell WL
Warren JE
Source :
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2009 Dec 14 (46), pp. 10169-71. Date of Electronic Publication: 2009 Oct 05.
Publication Year :
2009

Abstract

A chiral pseudo-C(3)-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.

Details

Language :
English
ISSN :
1477-9234
Issue :
46
Database :
MEDLINE
Journal :
Dalton transactions (Cambridge, England : 2003)
Publication Type :
Academic Journal
Accession number :
19921048
Full Text :
https://doi.org/10.1039/b918141p