Back to Search
Start Over
Lanthanide germanate cluster organic frameworks constructed from {Ln(8)Ge(12)} or {Ln(11)Ge(12)} cage cluster building blocks.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2009 Nov 04; Vol. 131 (43), pp. 15588-9. - Publication Year :
- 2009
-
Abstract
- Through the use of bis(carboxyethylgermanium) sesquioxide as the germanium source, lanthanide has been successfully introduced into germanate systems under hydrothermal conditions, resulting in a novel lanthanide germanate cluster organic framework with twofold-interpenetrating nets built from Nd(8)Ge(12) cluster units. To avoid the interpenetration, a second ligand, 2-picolinic acid, was introduced into the above system, resulting in the formation of a series of noninterpenetrating networks constructed from Ln(11)Ge(12) cluster units, as expected.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 131
- Issue :
- 43
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 19810735
- Full Text :
- https://doi.org/10.1021/ja906735v