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C2-symmetric S/C/S ligands based on N-heterocyclic carbenes: a new ligand architecture for asymmetric catalysis.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2009 Oct 28 (40), pp. 8485-8. Date of Electronic Publication: 2009 Aug 28. - Publication Year :
- 2009
-
Abstract
- Neutral, C2-symmetric S/C/S ligands based on N-heterocyclic carbenes and thioether functionalities were incorporated into transition metal complexes characterised by two direct metal-stereogenic sulfur bonds. This new ligand design was applied to 1,3-dipolar cycloadditions as the first example of the use silver of carbenes in asymmetric catalysis.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Issue :
- 40
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 19809722
- Full Text :
- https://doi.org/10.1039/b910846g