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Self assembly of silver(I) coordination polymers formed through hydrogen bonding with a new ditopic heteroscorpionate ligand.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2009 Sep 07 (33), pp. 6599-605. Date of Electronic Publication: 2009 Jul 02. - Publication Year :
- 2009
-
Abstract
- The new ditopic heteroscorpionate ligand, (3-methoxy-4-hydroxyphenyl)bis(3,5-dimethylpyrazolyl)methane (L5v), and four coordination polymers of silver Ag(i) derived therefrom, have been synthesized and characterized by X-ray diffraction, ESI-MS, IR spectroscopy and elemental analysis. The presence of different anions (i.e. BF4-, CF3SO3-, NO3-, or SbF6-) lead to different crystal packing schemes due to different H-bonding patterns that depend on the relative charge delocalization and/or shape of the anion.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Issue :
- 33
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 19672504
- Full Text :
- https://doi.org/10.1039/b906047b