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Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2009 Jul 28 (28), pp. 4206-8. Date of Electronic Publication: 2009 Jun 22. - Publication Year :
- 2009
-
Abstract
- Addition of PMe3 to Mo2(allyl)4 afforded Mo2(allyl)4(PMe3)2, in which two of the allyl groups adopt an unprecedented micro2-eta1,eta3 bonding mode; theoretical studies elucidate the roles of the sigma- and pi-donor ligands in the interplay of metal-allyl and metal-metal bonding.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 28
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 19585022
- Full Text :
- https://doi.org/10.1039/b908032e