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Highly oxidized diiron complexes: generation, spectroscopy, and stabilities.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2009 May 21 (19), pp. 2637-9. Date of Electronic Publication: 2009 Apr 07. - Publication Year :
- 2009
-
Abstract
- Oxidation of the diferric complex [LFe(III)OFe(III)L] to the monoradical complex [LFe(III)OFe(III)L ](+) and the diradical complex [L Fe(III)OFe(III)L ](2+) is followed by a decay into monomeric complexes including a highly reactive putative [LFe(IV)[double bond, length as m-dash]O] complex.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 19
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 19532905
- Full Text :
- https://doi.org/10.1039/b903500a