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A bimetallic pillared-layer metal-organic coordination framework with a 3D biporous structure.

Authors :
Maji TK
Pal S
Gurunatha KL
Govindaraj A
Rao CN
Source :
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2009 Jun 21 (23), pp. 4426-8. Date of Electronic Publication: 2009 Apr 20.
Publication Year :
2009

Abstract

A novel bimetallic [Mn(ii)-Fe(iii)] 3D biporous pillared-layer metal-organic coordination framework constructed by a cyanometallate anion ([Fe(CN)(6)](3-)) and an organic linker (4,4'-bipy) is found to exhibit permanent porosity with excellent size selective vapour sorption properties and H(2)-storage capability.

Details

Language :
English
ISSN :
1477-9226
Issue :
23
Database :
MEDLINE
Journal :
Dalton transactions (Cambridge, England : 2003)
Publication Type :
Academic Journal
Accession number :
19488436
Full Text :
https://doi.org/10.1039/b818498d