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Guest binding drives reversible atropisomerism in cavitand hosts.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2009 Jun 08; Vol. 15 (24), pp. 5892-5. - Publication Year :
- 2009
-
Abstract
- Guest-love-ometer: The equilibrium inside-outside atropisomeric ratio of ortho-substituted phenyl cavitands shows a strong solvent dependence. The competition between the ortho-substituent and the solvent guest for the bowl cavity leads to a sensitive system for the measurement of relative guest binding affinities.
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 15
- Issue :
- 24
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 19437468
- Full Text :
- https://doi.org/10.1002/chem.200900695