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Spectroscopic characterization of a copper(III) trisuperoxide complex bearing both side-on and end-on ligands.
- Source :
-
The journal of physical chemistry. A [J Phys Chem A] 2009 May 07; Vol. 113 (18), pp. 5355-9. - Publication Year :
- 2009
-
Abstract
- The copper atom reacts with dioxygen in solid argon to form a mononuclear copper dioxygen complex Cu(eta(2)-O(2))(eta(1)-O(2))(2) bearing both side-on and end-on bonded O(2) ligands. The complex is characterized as being a trisuperoxide species with the copper center in its unusual +3 oxidation state. The Cu(III) trisuperoxide complex loses an end-on bonded superoxo ligand in forming the copper bisdioxygen complex under infrared irradiation.
Details
- Language :
- English
- ISSN :
- 1520-5215
- Volume :
- 113
- Issue :
- 18
- Database :
- MEDLINE
- Journal :
- The journal of physical chemistry. A
- Publication Type :
- Academic Journal
- Accession number :
- 19366239
- Full Text :
- https://doi.org/10.1021/jp902166x