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A versatile co(bisalen) unit for homogeneous and heterogeneous cooperative catalysis in the hydrolytic kinetic resolution of epoxides.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2009; Vol. 15 (16), pp. 3951-5. - Publication Year :
- 2009
-
Abstract
- Bisalen-very cooperative: A novel styryl-substituted, unsymmetrical bisalen is shown to be a versatile precursor to both soluble and insoluble cooperative catalysts for the hydrolytic kinetic resolution of epoxides. The unique bisalen motif ensures all catalysts derived from it have the necessary molecular-level ligand pairing needed for cooperative bimetallic catalytic reactions (see scheme).
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 15
- Issue :
- 16
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 19266511
- Full Text :
- https://doi.org/10.1002/chem.200900030