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A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2009; Vol. 15 (13), pp. 3056-60. - Publication Year :
- 2009
-
Abstract
- Two very distinct chemical reactions, yet a single catalyst: A gold complex promotes the formation of tertiary enamines from a variety of terminal and internal alkynes. Subsequent addition of a terminal alkyne to the reaction mixture affords allenes (see scheme).
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 15
- Issue :
- 13
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 19219866
- Full Text :
- https://doi.org/10.1002/chem.200802626