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Poly[[diaqua-mu-4,4'-bipyridine-dinitratodi-mu-L-tyrosinato-dicopper(II)]: a chiral two-dimensional coordination polymer.
- Source :
-
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2009 Jan; Vol. 65 (Pt 1), pp. m7-9. Date of Electronic Publication: 2008 Dec 06. - Publication Year :
- 2009
-
Abstract
- The title compound, [Cu(2)(C(9)H(10)NO(3))(2)(NO(3))(2)(C(10)H(8)N(2))(H(2)O)(2)](n), contains Cu(II) atoms and L-tyrosinate (L-tyr) and 4,4'-bipyridine (4,4'-bipy) ligands in a 2:2:1 ratio. Each Cu atom is coordinated by one amino N atom and two carboxylate O atoms from two L-tyr ligands, one N atom from a 4,4'-bipy ligand, a monodentate nitrate ion and a water molecule in an elongated octahedral geometry. Adjacent Cu atoms are bridged by the bidentate carboxylate groups into a chain. These chains are further linked by the bridging 4,4'-bipy ligands, forming an undulated chiral two-dimensional sheet. O-H...O and N-H...O hydrogen bonds connect the sheets in the [100] direction. This study offers useful information for the engineering of chiral coordination polymers with amino acids and 4,4'-bipy ligands by considering the ratios of the metal ion and organic components.
Details
- Language :
- English
- ISSN :
- 1600-5759
- Volume :
- 65
- Issue :
- Pt 1
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section C, Crystal structure communications
- Publication Type :
- Academic Journal
- Accession number :
- 19129599
- Full Text :
- https://doi.org/10.1107/S0108270108038985