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Chemoenzymatic synthesis of chiral 4,4'-bipyridyls and their metal-organic frameworks.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Nov 21 (43), pp. 5538-40. Date of Electronic Publication: 2008 Oct 09. - Publication Year :
- 2008
-
Abstract
- The first enantiopure 4,4'-bipyridyls, , , and have been prepared in four or five steps via bacterial dioxygenase-catalysed cis-dihydroxylation of 4-chloroquinoline and C-C coupling; ligands and are found to be effective building blocks for the preparation of chiral metal-organic frameworks as demonstrated with the rational synthesis of two pillared-grid structures [Zn(2)(fumarate)(2)(L)], which exhibit interesting structural and dynamic aspects.
- Subjects :
- Catalysis
Crystallography, X-Ray
Hydroxylation
Ligands
Models, Molecular
Molecular Structure
Organometallic Compounds chemistry
Pseudomonas putida enzymology
Pyridines chemistry
Sphingomonas enzymology
Stereoisomerism
Dioxygenases metabolism
Fumarates chemistry
Organometallic Compounds chemical synthesis
Pyridines chemical synthesis
Pyridines metabolism
Zinc chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 43
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 18997944
- Full Text :
- https://doi.org/10.1039/b812366g