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Unusual face-to-face pi-pi stacking interactions within an indigo-pillared M3(tpt)-based triangular metalloprism.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2008 Nov 28 (44), pp. 6110-2. Date of Electronic Publication: 2008 Sep 22. - Publication Year :
- 2008
-
Abstract
- A triangular metalloprism, [((CO)3Re(mu-2)Re(CO)3)3(mu3-1)2], self-assembled from Re2(CO)10, 2,4,6-tri-4-pyridyl-1,3,5-triazine (tpt, 1), and indigo (H2(2)), represents a fairly novel example of strong face-to-face pi-pi interactions between the central triazine rings of the tpt ligands that bow significantly inward distorting the prismatic structure.
Details
- Language :
- English
- ISSN :
- 1477-9226
- Issue :
- 44
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 18985240
- Full Text :
- https://doi.org/10.1039/b809489f