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"Soft" metallic contact to isolated C60 molecules.

Authors :
Glowatzki H
Bröker B
Blum RP
Hofmann OT
Vollmer A
Rieger R
Müllen K
Zojer E
Rabe JP
Koch N
Source :
Nano letters [Nano Lett] 2008 Nov; Vol. 8 (11), pp. 3825-9. Date of Electronic Publication: 2008 Oct 28.
Publication Year :
2008

Abstract

C60 adsorbed on a monolayer of hexaazatriphenylene-hexanitrile (HATCN) on Ag(111) is investigated by ultraviolet photoelectron spectroscopy (UPS) and scanning tunneling microscopy. UPS and quantum-mechanical modeling show that HATCN chemisorbed on Ag(111) displays metallic character. This metallic molecular layer decouples C60 electronically from the Ag substrate and simultaneously acts both as template for the stable adsorption of isolated C60 molecules at room temperature and as "soft" metallic contact for subsequently deposited molecules.

Details

Language :
English
ISSN :
1530-6984
Volume :
8
Issue :
11
Database :
MEDLINE
Journal :
Nano letters
Publication Type :
Academic Journal
Accession number :
18954123
Full Text :
https://doi.org/10.1021/nl8021797