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Expeditious total syntheses of natural allenic products via aromatic ring umpolung.
- Source :
-
Organic letters [Org Lett] 2008 Oct 16; Vol. 10 (20), pp. 4629-32. Date of Electronic Publication: 2008 Sep 19. - Publication Year :
- 2008
-
Abstract
- Concise diastereoselective syntheses of the marine (+/-)-panacene and terrestrial (+/-)-desbromopanacene have been achieved in a few steps based on a concept of "aromatic ring umpolung". The synthetic avenue to the (+/-)-panacene involved a novel oxymercuration strategy to produce the correct configuration of the bromoallene moiety.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 10
- Issue :
- 20
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 18800844
- Full Text :
- https://doi.org/10.1021/ol801921d