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A simple route to chiral phosphinous acid-boranes.

Authors :
Moraleda D
Gatineau D
Martin D
Giordano L
Buono G
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Jul 14 (26), pp. 3031-3. Date of Electronic Publication: 2008 Apr 22.
Publication Year :
2008

Abstract

We report a simple one-pot synthesis of enantiomerically enriched alkyl- and arylphenylphosphinous acid-borane starting from readily available (R(P))-(-)-menthylhydrogenophenylphosphinate and organolithium reagents.

Details

Language :
English
ISSN :
1359-7345
Issue :
26
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
18688338
Full Text :
https://doi.org/10.1039/b802817f