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Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin.

Authors :
Cuesta L
Tomat E
Lynch VM
Sessler JL
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Aug 28 (32), pp. 3744-6. Date of Electronic Publication: 2008 Jul 01.
Publication Year :
2008

Abstract

The synthesis of binuclear organometallic ruthenium complexes of an expanded porphyrin-type macrocycle is reported; pyrrolic hydrogen bonding donors were found to interact with ancillary ligands in the primary coordination sphere and to stabilize coordinated dioxygen in an eta(2)-fashion.

Details

Language :
English
ISSN :
1359-7345
Issue :
32
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
18685763
Full Text :
https://doi.org/10.1039/b807126h