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A straightforward synthesis of tetrameric estrone-based macrocycles.

Authors :
Ramírez-López P
de la Torre MC
Montenegro HE
Asenjo M
Sierra MA
Source :
Organic letters [Org Lett] 2008 Aug 21; Vol. 10 (16), pp. 3555-8. Date of Electronic Publication: 2008 Jul 23.
Publication Year :
2008

Abstract

A straightforward approach to macrocycles having four estrone-derived nuclei by the sequential Cu-catalyzed Huisgen azide-alkyne cycloaddition-Glaser-Eglington Cu homocoupling has been developed. Due to its efficiency and simplicity, this sequence is useful for application to different natural product scaffolds.

Details

Language :
English
ISSN :
1523-7052
Volume :
10
Issue :
16
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
18646766
Full Text :
https://doi.org/10.1021/ol801313g