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Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.
- Source :
-
Inorganic chemistry [Inorg Chem] 2008 Jun 16; Vol. 47 (12), pp. 5212-7. Date of Electronic Publication: 2008 May 10. - Publication Year :
- 2008
-
Abstract
- The topotactic reduction and subsequent fluorination of Sr7Mn4O15 yields a phase of composition Sr7Mn4O13F2. Characterization of this phase utilizing powder neutron diffraction and 19F NMR shows that the fluoride ions are located on a single anion site, the same crystallographic site that is vacant in the reduced intermediate Sr7Mn4O13.
Details
- Language :
- English
- ISSN :
- 0020-1669
- Volume :
- 47
- Issue :
- 12
- Database :
- MEDLINE
- Journal :
- Inorganic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 18470979
- Full Text :
- https://doi.org/10.1021/ic800066g