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The 8 : 1 : 1 ternary hybrid framework in the system [EDT-TTF +][1,4-bis(iodoethynyl)benzene][Re6Se8(CN)6]4-: dual noncovalent expression of the octahedral halogen-bond hexa-acceptor nanonode.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 May 21 (19), pp. 2194-6. Date of Electronic Publication: 2008 Apr 08. - Publication Year :
- 2008
-
Abstract
- Complementary shapes of the neutral symmetrical halogen-bond bis-donor core and octahedral inorganic cluster core prevent halogen-bonded polymers developing in more than one direction, favouring further templating by conducting radical cation slabs and yielding an 8 : 1 : 1 phase formulation instead of n : 2 : 1, with a 2D net, or m : 3 : 1, with a pseudo-cubic architecture, which may in principle also be targeted.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 19
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 18463737
- Full Text :
- https://doi.org/10.1039/b800571k