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A new NCN pincer ruthenium complex and its catalytic activity for enantioselective hydrogenation of ketones.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Apr 28 (16), pp. 1923-5. Date of Electronic Publication: 2008 Mar 12. - Publication Year :
- 2008
-
Abstract
- New bis(oxazolinyl)phenyl-ruthenium(II) complexes, which were synthesized by C-H bond activation with RuCl(3).3H(2)O in zinc powder and 1,5-cyclooctadine followed by ligand exchange reaction with sodium acetylacetonate or acetylacetone, exhibited enantioselective hydrogenation of ketones in up to 90% ee.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 16
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 18401520
- Full Text :
- https://doi.org/10.1039/b800387d