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The mechanism of carbonate formation on Pd-Al2O3 catalysts.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Jan 21 (3), pp. 320-2. - Publication Year :
- 2008
-
Abstract
- Vibrational spectroscopic investigations of the adsorption of isotopically labelled and unlabelled CO and CO2 reveal that carbonate formation on Pd-alumina catalysts occurs via an "oxygen down" reaction of CO with hydroxyl groups on the support, whereas CO dissociation on Pd can be excluded.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 3
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 18399194
- Full Text :
- https://doi.org/10.1039/b713161e