The synthesis, crystal structure and spectroscopic properties of luminescent Zn(II) complex.

Authors :: Cai P
Hou JR
Liu TS
Cheng GZ
Peng TY
Peng ZH
Source :: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy [Spectrochim Acta A Mol Biomol Spectrosc] 2008 Nov 15; Vol. 71 (2), pp. 584-7. Date of Electronic Publication: 2008 Jan 16.
Publication Year :: 2008
Abstract: A luminescent Zn(II) complex 1, ZnL2Cl2.2H2O has been synthesized where L=2,2',2''-(1,3,5-benzenetriyltrimethylidyne) as a yellow crystal. Single crystal X-ray analysis of the compound 1 shows a distorted tetrahedral structure. The compound 1 crystallizes in monoclinic, space group C2/c with a = 20.3151(19), b = 8.7299(9), c = 24.626(2) angstroms, beta = 107.474(2) degrees , V = 4165.9(7) A3. At room temperature, the complex 1 exhibits an intense blue emission at 474 nm upon 380 nm excitation.

Subjects :: Crystallography, X-Ray
Fluorescent Dyes chemistry
Hydrogen Bonding
Models, Molecular
Molecular Structure
Zinc Compounds chemistry
Fluorescent Dyes chemical synthesis
Zinc Compounds chemical synthesis

Language :: English
ISSN :: 1386-1425
Volume :: 71
Issue :: 2
Database :: MEDLINE
Journal :: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
Publication Type :: Academic Journal
Accession number :: 18280779
Full Text :: https://doi.org/10.1016/j.saa.2008.01.011

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