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A study of the effect of Z- and E-olefinic geometry on the rates of ring closure of 13-membered dienes.

Authors :
Liau BB
Gnanadesikan V
Corey EJ
Source :
Organic letters [Org Lett] 2008 Mar 20; Vol. 10 (6), pp. 1055-7. Date of Electronic Publication: 2008 Feb 15.
Publication Year :
2008

Abstract

An analysis is presented to explain the faster rate of ring formation 5 --> 7 as compared to 6 --> 8.

Subjects

Subjects :
Cyclization
Alkenes chemistry

Details

Language :
English
ISSN :
1523-7060
Volume :
10
Issue :
6
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
18275205
Full Text :
https://doi.org/10.1021/ol702868z