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A twofold parallel interpenetration network from the assembly of a flexible spacer and CuI: poly[micro-iodido-micro-4,4'-(methylenedithio)dipyridine-kappa2N:N'-copper(I)].
- Source :
-
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2008 Feb; Vol. 64 (Pt 2), pp. m76-8. Date of Electronic Publication: 2008 Jan 12. - Publication Year :
- 2008
-
Abstract
- The title compound, [CuI(C(11)H(10)N(2)S(2))](n), is built around centrosymmetric dinuclear Cu(2)I(2) cores, each of which is linked to four neighboring Cu(2)I(2) units via flexible dithioether ligands, viz. 4,4'-(methylenedithio)dipyridine, to form a two-dimensional grid containing rhombus-shaped cavities with diagonal distances of ca 15 and 22 A. Two of these networks interpenetrate in a woven fashion, and the resulting structure does not possess any open channels or cavities. Each Cu atom is in a distorted tetrahedral coordination environment.
Details
- Language :
- English
- ISSN :
- 1600-5759
- Volume :
- 64
- Issue :
- Pt 2
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section C, Crystal structure communications
- Publication Type :
- Academic Journal
- Accession number :
- 18252991
- Full Text :
- https://doi.org/10.1107/S0108270107064669