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Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Jan 14 (2), pp. 187-9. Date of Electronic Publication: 2007 Nov 13. - Publication Year :
- 2008
-
Abstract
- In a new type of reactivity for sodium TMP-zincate [(TMEDA)NaZn((t)Bu)(2)(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-alpha-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H).
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 2
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 18092082
- Full Text :
- https://doi.org/10.1039/b713987j