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Preparation and X-ray structures of 3-[Bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy(tosyloxy)iodo]benzoic acid: new recyclable hypervalent iodine reagents.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2008 Jan 04; Vol. 73 (1), pp. 295-7. Date of Electronic Publication: 2007 Dec 07. - Publication Year :
- 2008
-
Abstract
- Preparation, structural characterization, and reactivity of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy(tosyloxy)iodo]benzoic acid, new recyclable iodine(III) reagents derived from 3-iodosylbenzoic acid, are described. The reduced form of these reagents, 3-iodobenzoic acid, can be easily recovered from the reaction mixtures using ion-exchange resin or basic aqueous workup followed by acidification with HCl.
- Subjects :
- Crystallography, X-Ray
Fluoroacetates
Indicators and Reagents chemical synthesis
Indicators and Reagents chemistry
Iodobenzoates
Models, Molecular
Molecular Structure
Stereoisomerism
Benzoates chemical synthesis
Benzoates chemistry
Hydrocarbons, Iodinated chemical synthesis
Hydrocarbons, Iodinated chemistry
Tosyl Compounds chemical synthesis
Tosyl Compounds chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 0022-3263
- Volume :
- 73
- Issue :
- 1
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 18062703
- Full Text :
- https://doi.org/10.1021/jo702112s