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Oxidative degradations of the side chain of unsaturated ent-labdanes. Part I.

Authors :
Espinoza Catalán L
Carrasco Altamirano H
Cuellar Fritis M
Gallardo Araya C
Catalán Marín K
Source :
Molecules (Basel, Switzerland) [Molecules] 2007 Mar 06; Vol. 12 (3), pp. 318-27. Date of Electronic Publication: 2007 Mar 06.
Publication Year :
2007

Abstract

A selective route for the degradation of the unsaturated side chain of ent-labdanes has been devised, giving two useful synthons: 2beta-acetoxy-14,15,17-trinor-ent-labdane-8,13- dione (5) and 2beta-acetoxy-14,15-dinor-ent-labd-8(17)-en-13-one (7), the use of which for the preparation of terpenylquinone derivatives shall be reported elsewhere.

Details

Language :
English
ISSN :
1420-3049
Volume :
12
Issue :
3
Database :
MEDLINE
Journal :
Molecules (Basel, Switzerland)
Publication Type :
Academic Journal
Accession number :
17851391
Full Text :
https://doi.org/10.3390/12030318