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Sc3N@C78: encapsulated cluster regiocontrol of adduct docking on an ellipsoidal metallofullerene sphere.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2007 Sep 05; Vol. 129 (35), pp. 10795-800. Date of Electronic Publication: 2007 Aug 10. - Publication Year :
- 2007
-
Abstract
- The first N-tritylpyrrolidino derivatives of D(3h) (78:5) Sc(3)N@C(78) were successfully synthesized and isolated. The addition sites for the two nearly equivalent kinetic monoadducts 1a and 1b are across two different 6,6 junction sites on the Sc(3)N@C(78) cage that are offset from the horizontal plane defined by the Sc(3)N cluster. The adducts were characterized by NMR experiments, DFT calculations and X-ray crystallographic analysis of Sc(3)N@C(78) derivative 1a. A unique finding of this study is the regiocontrol of adduct docking by the internal Sc(3)N cluster.
Details
- Language :
- English
- ISSN :
- 0002-7863
- Volume :
- 129
- Issue :
- 35
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 17691732
- Full Text :
- https://doi.org/10.1021/ja072345o