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A simple method to determine kinetic deuterium isotope effects provides evidence that proton transfer to carbon proceeds over and not through the reaction barrier.

Authors :
Tsang WY
Richard JP
Source :
Journal of the American Chemical Society [J Am Chem Soc] 2007 Aug 29; Vol. 129 (34), pp. 10330-1. Date of Electronic Publication: 2007 Aug 04.
Publication Year :
2007

Details

Language :
English
ISSN :
0002-7863
Volume :
129
Issue :
34
Database :
MEDLINE
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
17676848
Full Text :
https://doi.org/10.1021/ja073679g