Photolysis of an alkoxyamine using intramolecular energy transfer from a quinoline antenna--towards photo-induced living radical polymerization.

Authors :: Goto A
Scaiano JC
Maretti L
Source :: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology [Photochem Photobiol Sci] 2007 Aug; Vol. 6 (8), pp. 833-5. Date of Electronic Publication: 2007 Jul 13.
Publication Year :: 2007
Abstract: The photolysis of an alkoxyamine triad comprised of the 1-phenylethyl moiety, 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and 2-methyl-3-hydroxy quinoline leads to energy transfer from the quinoline moiety (antenna) and cleavage of the C-O alkoxyamine bond, suggesting its possible applications in low temperature living free radical polymerization.

Language :: English
ISSN :: 1474-905X
Volume :: 6
Issue :: 8
Database :: MEDLINE
Journal :: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
Publication Type :: Academic Journal
Accession number :: 17668111
Full Text :: https://doi.org/10.1039/b705671k

Full Text Access

Tools