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Zirconium-catalyzed heterodehydrocoupling of primary phosphines with silanes and germanes.
- Source :
-
Inorganic chemistry [Inorg Chem] 2007 Aug 20; Vol. 46 (17), pp. 6855-7. Date of Electronic Publication: 2007 Jul 25. - Publication Year :
- 2007
-
Abstract
- Triamidoamine-supported zirconium complexes catalyze the heterodehydrocoupling of primary phosphines with silane and germanes. In this catalysis, P-Si or P-Ge products are observed exclusively with no competitive P-P bond formation. Phosphido complexes (N3N)ZrPHR (N3N = N(CH2CH2NSiMe3)33-, R = Ph, 2; Cy, 3) were observed to be the catalyst resting state, and complex 2 was structurally characterized.
Details
- Language :
- English
- ISSN :
- 0020-1669
- Volume :
- 46
- Issue :
- 17
- Database :
- MEDLINE
- Journal :
- Inorganic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 17649993
- Full Text :
- https://doi.org/10.1021/ic7013144